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A neutral good character does good for goodness' sake, not because she or he is directed to by law or by whim. Such characters will obey the law or break it when they see that it will serve a greater good. They aren't bound strongly to a social system or order. Their need to help others and reduce suffering may take precedence over all else.
A doctor who treats both sides in a fight and somebody who feeds the starving in a war zone are both examples of neutral good characters.
Some characters in the Forgotten Realms setting identified as Neutral Good include: